Please use this identifier to cite or link to this item: http://nopr.niscair.res.in/handle/123456789/45177
Title: N-Arylation of heterocycles by mixed ligand transition metal complexes under mild conditions
Authors: Hegade, S S
Gaikwad, G A
Mulik, G N
Keywords: Quinazolinone Schiff base;Mixed ligand transition metal complex;N-arylation;Heterocycles
Issue Date: Oct-2018
Publisher: NISCAIR-CSIR, India
Abstract: Mixed ligand transition metal complexes [M(L)(PPh3)2]X2 1-4 where L- 2-phenyl, 3-benzoylamino-1,2-dihydroquinazolin-4(3H)-one (PBADQ), where M is Co, Ni, Cu, Zn and X is Cl have been synthesized and characterized by elemental analysis, IR, NMR spectral studies and their role as catalyst in N-arylation of indole and isatin with aryl halides. It has been observed that all the complexes worked as efficient catalysts, especially [Ni(L)(PPh3)2]Cl2 complex 2 is found to be most suitable for N-arylation of indole and isatin.
Page(s): 1304-1309
URI: http://nopr.niscair.res.in/handle/123456789/45177
ISSN: 0975-0983(Online); 0376-4699(Print)
Appears in Collections:IJC-B Vol.57B(10) [October 2018]

Files in This Item:
File Description SizeFormat 
IJCB 57B(10) 1304-1309.pdfMain Article403.98 kBAdobe PDFView/Open
IJCB 57B(10) 1304-1309_Suppl Data.pdfSupplementary Data923.95 kBAdobe PDFView/Open


Items in NOPR are protected by copyright, with all rights reserved, unless otherwise indicated.