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Title: Synthesis, crystal structure and properties of a 3D zinc(II) coordination polymer with asymmetric 3-amino-1,2,4-triazolate
Authors: Fan, Wen Tao
Du, Jiao Jiao
Xu, Quan Qing
Kou, Jun Feng
Liu, Feng Yi
Keywords: Coordination polymers;3D-Framework;X-ray structure;Fluorescence;Zinc sulfate;Triazoles;Symmetric triazoles
Issue Date: Aug-2018
Publisher: NISCAIR-CSIR, India
Abstract: A new coordination polymer, [Zn2SO4(atz)2(H2O)2]·(H2O)4 (1) (Hatz = 1H-3-amino-1,2,4-triazole) has been synthesized using zinc sulfate and an asymmetric 3-substituted triazole ligand at room temperature. X-ray analysis reveals that complex 1 shows a 3D-framework containing Zn2(atz)2(H2O)2SO4 subunits, which display a 6-coordinated unimodal pcu topological network. Further, complex 1 exhibits purple fluorescence with an emission maximum at 405 nm in the solid state at room temperature.
Page(s): 1133-1137
ISSN: 0975-0975(Online); 0376-4710(Print)
Appears in Collections:IJC-A Vol.57A(08-09) [August-September 2018]

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IJCA 57A(8-9) 1133-1137.pdfMain Article443.43 kBAdobe PDFView/Open
IJCA 57A(8-9) 1133-1137_Suppl Data.pdfSupplementary Data646.05 kBAdobe PDFView/Open
IJCA 57A(8-9) 1133-1137_Suppl Data_cif.pdfSuppl Crystellographic Data 1228.85 kBAdobe PDFView/Open

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