Please use this identifier to cite or link to this item:
|Title:||Formation of esters and amides via metal-free Csp2-Csp3 bond cleavage of α-nitro ketone: Mechanistic insight to the reaction pathway|
|Authors:||Sarma, Manas Jyoti|
|Abstract:||A catalyst free protocol for nucleophilic Csp2-Csp3 bond cleavage of α-nitroketone has been achieved for the formation of C-O and C-N bond. A series of differently substituted α-nitroketones could be selectively cleaved and converted into corresponding esters and tosylamides in presence of alcohols and bromamine-T respectively. Mechanism of the C-C bond cleavage has been proposed by identifying different reaction intermediates using IR and NMR spectroscopic methods.|
|Appears in Collections:||IJC-B Vol.57B(04) [April 2018]|
Items in NOPR are protected by copyright, with all rights reserved, unless otherwise indicated.