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|Title:||Kinetics and mechanism of palladium(II) catalysed oxidation of some hydroxyacids by N-bromosuccinimide in perchloric acid medium|
Upadhyay, S K
|Abstract:||The kinetics of oxidation of palladium(II) catalysed oxidation of some hydroxyacids, viz, malic, citric and tartaric acids by N- bromosuccinimide have been studied in perchloric acid medium in the presence of mercuric acetate. A first order dependence of rate each in [oxidant] and [catalyst] has been observed. The order of reaction in substrate decreases at higher [substrate]. A retarding effect of [H+] on the rate has also been observed. A suitable mechanism consistent with observed kinetic data is proposed and discussed.|
|Appears in Collections:||IJC-A Vol.32A(12) [December 1993]|
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