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Title: Kinetics and mechanism of palladium(II) catalysed oxidation of some hydroxyacids by N-bromosuccinimide in perchloric acid medium
Authors: Saxena, Rashmi
Upadhyay, S K
Issue Date: Dec-1993
Publisher: NISCAIR-CSIR, India
Abstract: The kinetics of oxidation of palladium(II) catalysed oxidation of some hydroxyacids, viz, malic, citric and tartaric acids by N- bromosuccinimide have been studied in perchloric acid medium in the presence of mercuric acetate. A first order dependence of rate each in [oxidant] and [catalyst] has been observed. The order of reaction in substrate decreases at higher [substrate]. A retarding effect of [H+] on the rate has also been observed. A suitable mechanism consistent with observed kinetic data is proposed and discussed.
Page(s): 1060-1063
ISSN: 0975-0975(Online); 0376-4710(Print)
Appears in Collections:IJC-A Vol.32A(12) [December 1993]

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