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dc.contributor.authorSrinivasan, C-
dc.contributor.authorRadhakrishnan, K-
dc.contributor.authorShunmugasundaram, A-
dc.identifier.issn0975-0975(Online); 0376-4710(Print)-
dc.description.abstractThe kinetics of addition of diethylamine to ethyl ɑ-cyanocinnamates and para-substituted ethyl ɑ-cyanocinnamates in acetonitrile at four different temperatures have been followed spectrophotometrically. A step wise mechanism involving the formation of zwitteri-onic addition complex in an equilibrium step followed by conversion into the reaction product via proton transfer has been proposed for the second order addition reaction and this also accounts for the observed structure-reactivity pattern (ρ = 1.02 ±0.11 at 30ᵒC).en_US
dc.publisherNISCAIR-CSIR, Indiaen_US
dc.rights CC Attribution-Noncommercial-No Derivative Works 2.5 Indiaen_US
dc.sourceIJC-A Vol.32A(12) [December 1993]en_US
dc.titleKinetics of addition of diethylamine to para-substituted ethyl ɑ-cyanocinnamatesen_US
Appears in Collections:IJC-A Vol.32A(12) [December 1993]

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