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Title: Homolytic displacement at saturated carbon in organocobaloximes: Part VI† - Synthesis of benzyl sulphones
Authors: Gupta, B D
Das, Indira
Dixit, Yandana
Issue Date: Sep-1993
Publisher: NISCAIR-CSIR, India
Abstract: The reactions of thiophene-2-sulphonyl chloride with benzyl and para-substituted benzyl cobaloximes under anaerobic and photochemical conditions at 0°C give benzyl sulphones and bibenzyls in variable yields. However, the reactions with heteroaromatic methyl cobaloximes give the corresponding sulphones as the exclusive organic products. The reactions are interpreted in terms of SH2 mechanism.
Page(s): 762-766
ISSN: 0975-0975(Online); 0376-4710(Print)
Appears in Collections:IJC-A Vol.32A(09) [September 1993]

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