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|Title:||Homolytic displacement at saturated carbon in organocobaloximes: Part VI† - Synthesis of benzyl sulphones|
|Authors:||Gupta, B D|
|Abstract:||The reactions of thiophene-2-sulphonyl chloride with benzyl and para-substituted benzyl cobaloximes under anaerobic and photochemical conditions at 0°C give benzyl sulphones and bibenzyls in variable yields. However, the reactions with heteroaromatic methyl cobaloximes give the corresponding sulphones as the exclusive organic products. The reactions are interpreted in terms of SH2 mechanism.|
|Appears in Collections:||IJC-A Vol.32A(09) [September 1993]|
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