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Title: Kinetics of oxidation of bisulphite ion by iron (III) in the presence of 1,10-phenanthroline
Authors: Mohapatra, S K
Issue Date: Aug-1993
Publisher: NISCAIR-CSIR, India
Abstract: The title reaction has been investigated under pseudo-unimolecular conditions with [phen] > [HSO] > [Fe(III)]. The reaction obeys first order kinetics in [Fe(III)]. The kinetics is interpreted in terms of an inner-sphere reduction of Fe(phen) via formation of the reactive intermediate Fe(phen)2-(SO3H)2+.
Page(s): 709-710
ISSN: 0975-0975(Online); 0376-4710(Print)
Appears in Collections:IJC-A Vol.32A(08) [August 1993]

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