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|Title:||Kinetics of oxidation of bisulphite ion by iron (III) in the presence of 1,10-phenanthroline|
|Authors:||Mohapatra, S K|
|Abstract:||The title reaction has been investigated under pseudo-unimolecular conditions with [phen] > [HSO] > [Fe(III)]. The reaction obeys first order kinetics in [Fe(III)]. The kinetics is interpreted in terms of an inner-sphere reduction of Fe(phen) via formation of the reactive intermediate Fe(phen)2-(SO3H)2+.|
|Appears in Collections:||IJC-A Vol.32A(08) [August 1993]|
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