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Title: Stereoselective carbon–carbon bond formation via 1,2-asymmetric induction by a β-substituent in the reaction of α-chloro sulfides with organozinc reagents
Authors: Raghavan, S
Chowhan, L Raju
Keywords: α-Chlorosulfide;Organozinc reagents;1,2-asymmetric induction;Chiral α-substituted sulfides
Issue Date: Mar-2018
Publisher: NISCAIR-CSIR, India
Abstract: The stereoselectivity of C–C bond formation in the reaction of α-chlorosulfides with a variety of organozinc reagents has been investigated. The study reveals excellent 1,2-asymmetric induction by a β-siloxy substituent and moderate 1,2-induction by the β-methyl substituent. The stereoselectivity is a function of the size of the organozinc reagents.
Page(s): 327-339
ISSN: 0975-0983(Online); 0376-4699(Print)
Appears in Collections:IJC-B Vol.57B(03) [March 2018]

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