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|Title:||Stereoselective carbon–carbon bond formation via 1,2-asymmetric induction by a β-substituent in the reaction of α-chloro sulfides with organozinc reagents|
Chowhan, L Raju
|Keywords:||α-Chlorosulfide;Organozinc reagents;1,2-asymmetric induction;Chiral α-substituted sulfides|
|Abstract:||The stereoselectivity of C–C bond formation in the reaction of α-chlorosulfides with a variety of organozinc reagents has been investigated. The study reveals excellent 1,2-asymmetric induction by a β-siloxy substituent and moderate 1,2-induction by the β-methyl substituent. The stereoselectivity is a function of the size of the organozinc reagents.|
|Appears in Collections:||IJC-B Vol.57B(03) [March 2018]|
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