Please use this identifier to cite or link to this item: http://nopr.niscair.res.in/handle/123456789/43804
Title: Reactions of M{Al(OPri)4}2 and ClM{Al(OPri)4}[M=Zn(II) and Cd(II)] with methoxyethanol
Authors: Sogani, S
Singh, A
Mehrotra, R C
Issue Date: Apr-1993
Publisher: NISCAIR-CSIR, India
Abstract: Reactions of M{MAl(OPri)4}2 and CIM{Al(OPri)4} [M = Zn(II) or Cd(II)] with methoxyethanol in different molar ratios in benzene yield derivatives of the types, [M{Al(OPri)4-n (OCH2CH2OMe)n}2 [M = Zn(II) or Cd(II), n = 1, 2, 3, 4] and CIM{Al(OPri)4-n (OCH2CH2OMe)n} [M= Zn(II) or Cd(II), n = 2, 4]. Soluble homometallic methoxyethoxides of zinc and cadmium, M(OCH2CH2OMe)2, have also been prepared by the reactions of MCl2 with NaOCH2CH2OMe in 1:2 molar ratio in a mixture of methoxyethanol and benzene. All these derivatives have been characterized by elemental analysis, infrared and NMR (lH, 13C and 27A1) spectroscopy as well as by molecular weight studies.
Page(s): 345-350
URI: http://nopr.niscair.res.in/handle/123456789/43804
ISSN: 0975-0975(Online); 0376-4710(Print)
Appears in Collections:IJC-A Vol.32A(04) [April 1993]

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