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Title: Synthesis of a new heteronuclear tin-cobalt cluster complex
Authors: Ullah, S S
Kundu, K
Karim, M M
Hossain, M F
Quyser, M A
Issue Date: Mar-1993
Publisher: NISCAIR-CSIR, India
Abstract: A new heteronuclear tin-cobalt cluster complex, [Bu8Sn4Co4(CO)6(DPPE)] (II), has been synthesized by thermal reaction of dibutylbis(tetracarbonylcobalt) tin(lV), BU2Sn[Co (CO)4 ]2 (I), with bis(diphenylphosphino)ethane (DPPE) in n-hexane. The complex (II) has a tetrahedral frame-work of four cobalt atoms with BU2Sn: bridging across the apices of the tetrahedron on opposite faces. A condensation-elimination process is tentatively suggested for the reaction.
Page(s): 257-258
ISSN: 0975-0975(Online); 0376-4710(Print)
Appears in Collections:IJC-A Vol.32A(03) [March 1993]

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