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Title: Two directional approach to spirocycles containing bicyclo[2.2.2]octane system via a [2+2+2] co-trimerization and Diels-Alder reaction
Authors: Kotha, Sambasivarao
Saifuddin, Mohammad
Ali, Rashid
Shirbhate, Mukesh E
Sreevani, Gaddamedi
Keywords: Bicyclo[2.2.2]octane;Spirocycles;[2+2+2] co-trimerization;DA reaction;Sulfone
Issue Date: Dec-2017
Publisher: NISCAIR-CSIR, India
Abstract: A simple and atom economic/step economic route for the synthesis of bis-armed spirocycles including bis-armed spirosulfone derivative containing bicyclo[2.2.2]octane ring system by utilizing a MW assisted Mo(CO)6 catalyzed two-directional [2+2+2] co-trimerization and the [4+2] cycloaddition reaction as key steps, is reported.
Page(s): 1231-1236
ISSN: 0975-0983(Online); 0376-4699(Print)
Appears in Collections:IJC-B Vol.56B(12) December 2017]

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