Please use this identifier to cite or link to this item: http://nopr.niscair.res.in/handle/123456789/42314
Title: Synthesis and crystal structures of pyridine- 2-carboxaldehyde thiosemicarbazone, its mononuclear and cytotoxic Cu(II) and polynuclear Pb(II) complexes: Effect of size of metal ion on nucleation of the complexes
Authors: Ghosh, Ayon Kanti
Yadav, Hare Ram
Choudhury, Angshuman Roy
Duraipandian, N
Kiran, Manikantan Symala
Ghosh, Rajarshi
Keywords: Coordination chemistry;Thiosemicarbazones;Copper;Lead;Anticancer activity;X-ray structure
Issue Date: Jun-2017
Publisher: NISCAIR-CSIR, India
Abstract: Synthesis and X-ray structural characterization of pyridine-2-carboxaldehyde thiosemicarbazone (L), and its metal complexes, [Cu(L)(OH2)](ClO4)2 and [Pb(L)(ONO2)2]n are reported. X-ray diffraction reveals that the metal centres in the two complexes are distorted square planar and square pyramid geometries, respectively. Among the three compounds [Cu(L)(OH2)](ClO4)2 is found to be active against human keratinocyte cell line.
Page(s): 616-620
URI: http://nopr.niscair.res.in/handle/123456789/42314
ISSN: 0975-0975(Online); 0376-4710(Print)
Appears in Collections:IJC-A Vol.56A(06) [June 2017]

Files in This Item:
File Description SizeFormat 
IJCA 56A(6) 616-620.pdfMain Article223.65 kBAdobe PDFView/Open
IJCA 56A(6) 616-620_SupplData.pdfSupplementary Data103.69 kBAdobe PDFView/Open
IJCA 56A(6) 616-620_SupplData_cif-Cu.cifSuppl Crystellographic Data 1312.33 kBUnknownView/Open
IJCA 56A(6) 616-620_SupplData_cif-L.cifSuppl Crystellographic Data 2513.44 kBUnknownView/Open
IJCA 56A(6) 616-620_SupplData_cif-Pb.cifSuppl Crystellographic Data 3626.18 kBUnknownView/Open


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