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|Title:||Substitution reaction of aqua ligand from hexaaquochromium(III) ion by pyridine- 2-aldoxime: A kinetic study|
De, G S
|Abstract:||Kinetics of substitution of aqua ligands from hexaaquochromium(III) ion by pyridine-2-aldoxime in aqueous medium has been studied spectrophotometrically. The reaction rate is pH dependent in the pH range 2.0- 5.0. Activation parameters have been calculated and compared with those for the water exchange reaction and other substitution reactions of hexaaquochromium(III) ion. A mechanism involving conversion of the outer sphere complex into the product by associative path has been suggested.|
|Appears in Collections:||IJC-A Vol.30A(12) [December 1991]|
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