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Title: Substitution reaction of aqua ligand from hexaaquochromium(III) ion by pyridine- 2-aldoxime: A kinetic study
Authors: De, Pompa
De, G S
Issue Date: Dec-1991
Publisher: NISCAIR-CSIR, India
Abstract: Kinetics of substitution of aqua ligands from hexaaquochromium(III) ion by pyridine-2-aldoxime in aqueous medium has been studied spectrophotometrically. The reaction rate is pH dependent in the pH range 2.0- 5.0. Activation parameters have been calculated and compared with those for the water exchange reaction and other substitution reactions of hexaaquochromium(III) ion. A mechanism involving conversion of the outer sphere complex into the product by associative path has been suggested.
Page(s): 1050-1052
ISSN: 0975-0975(Online); 0376-4710(Print)
Appears in Collections:IJC-A Vol.30A(12) [December 1991]

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