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|Title:||Synthesis and characterisation of copper(II) complexes having N2S†S and N2S†O (s† = thioether) donor sets|
Bharadwaj, P K
|Abstract:||Synthesis of a ligand bearing the donor set resembling that for the type 1 active sites of some of the blue proteins is described. This ligand forms a four coordinate complex with copper(II) perchlorate; the complex has been characterised on the basis of various physicochemical studies. To facilitate the characterisation, the oxygen analogue of the thiolate ligand has also been prepared which also forms a four-coordinate complex with copper perchlorate, like the thiolate ligand. Present study is the first example of a copper(II) complex having donors similar to those present at the blue copper active site in some proteins.|
|Appears in Collections:||IJC-A Vol.30A(11) [November 1991]|
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