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Title: Synthesis and characterisation of copper(II) complexes having N2SS and N2SO (s = thioether) donor sets
Authors: Mandal, S
Bharadwaj, P K
Issue Date: Nov-1991
Publisher: NISCAIR-CSIR, India
Abstract: Synthesis of a ligand bearing the donor set resembling that for the type 1 active sites of some of the blue proteins is described. This ligand forms a four coordinate complex with copper(II) perchlorate; the complex has been characterised on the basis of various physicochemical studies. To facilitate the characterisation, the oxygen analogue of the thiolate ligand has also been prepared which also forms a four-coordinate complex with copper perchlorate, like the thiolate ligand. Present study is the first example of a copper(II) complex having donors similar to those present at the blue copper active site in some proteins.
Page(s): 948-951
ISSN: 0975-0975(Online); 0376-4710(Print)
Appears in Collections:IJC-A Vol.30A(11) [November 1991]

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