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Title: Photochemical studies on manganese-quinone complexes: Part 1- Photoinduced intramolecular electron transfer in bis(aquo)bis(phthiocolato) manganese(II)
Authors: Yerande, RatnamaIa
Mulay, Mahesh
Padhye, Subhash
Ramamurthy, P
Natarajan, P
Issue Date: Jul-1991
Publisher: NISCAIR-CSIR, India
Abstract: [Mn(II)(phth)2(H2O)2] complex (phth =anion of 2-methyl-3-hydroxy-1,4-naphthoquinone), after the xenon lamp flash photolysis in ethanol undergoes an intramolecular electron transfer involving oxidation of manganese(II) center and generation of a semiquinone species.This isconfirmedby optical and EPR spectra indicating charge transfer to ligand (CTTL) photochemistry.
Page(s): 575-578
ISSN: 0975-0975(Online); 0376-4710(Print)
Appears in Collections:IJC-A Vol.30A(07) [July 1991]

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