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Title: Kinetics and mechanism of ruthenium(III) catalysed oxidation of amines by Ce(IV) in acid medium
Authors: Rao, N Nageshwar
Rao, M Anand
Issue Date: Jul-1991
Publisher: NISCAIR-CSIR, India
Abstract: Ruthenium(III) catalysed oxidation of methyl, ethyl, butyl, dimethyl and trimethyl amines by Ce(IV) in nitric acid has been found to be acid dependent. Ru(III)-catalysis of Ce(IV)-amine reaction is explained in terms of formation of a 1:1 complex between Ru(III) and amine which later reacts with Ce(IV) to give the products, namely, ammonia and the corresponding aldehyde or ketone.
Page(s): 620-622
ISSN: 0975-0975(Online); 0376-4710(Print)
Appears in Collections:IJC-A Vol.30A(07) [July 1991]

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