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|Title:||Kinetics and mechanism of ruthenium(III) catalysed oxidation of amines by Ce(IV) in acid medium|
|Authors:||Rao, N Nageshwar|
Rao, M Anand
|Abstract:||Ruthenium(III) catalysed oxidation of methyl, ethyl, butyl, dimethyl and trimethyl amines by Ce(IV) in nitric acid has been found to be acid dependent. Ru(III)-catalysis of Ce(IV)-amine reaction is explained in terms of formation of a 1:1 complex between Ru(III) and amine which later reacts with Ce(IV) to give the products, namely, ammonia and the corresponding aldehyde or ketone.|
|Appears in Collections:||IJC-A Vol.30A(07) [July 1991]|
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