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Title: Mixed ligand complexes of ruthenium (II) with α,β-unsaturated β –ketoamines
Authors: Muthusamy, G
Natarajan, K
Issue Date: Jul-1991
Publisher: NISCAIR-CSIR, India
Abstract: Ruthenium (II) mixed ligand complexes of the type [RuH(CO)(LL )(PPh)3)2 ] and [RuCl(CO)(LL') (PPh)3)2 LL' =α,β-unsaturated-β-ketoaminate) have been synthes sed by the replace ent of Hand PPh3, by a bidentate ch lating ligand, α,β-unsaturated- β -ketoamine, from [RuH2(CO) (PPh)3)3 and [RuHCl(CO) (PPh)3)3 respectively. All the complexes have been assigned octahedral structures on the basis of elemental analyses, IR, 1H NMR and electronic spectral data.
Page(s): 626-628
ISSN: 0975-0975(Online); 0376-4710(Print)
Appears in Collections:IJC-A Vol.30A(07) [July 1991]

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