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Title: Synthesis of some bimetallic complexes of cobalt(II), nickel(II) and copper(II) oximates with antimony
Authors: Singh, S V
Gupta, S
Ojha, A C
Rastogi, M K
Issue Date: Jun-1991
Publisher: NISCAIR-CSIR, India
Abstract: Someoximates of cobalt(II), nickel(II)and copper(II) on reacting with antimony trichloride in dimethylformarnidegivebimetalliccomplexeswith the liberation of HCl. ϒ-Benzildioximates give bimetallic adducts. Cobalt(II) and nickel(II) Schiff base complexeson further reaction with antimony trichloride give bimetallic adducts in which a geometrical transformation in the stereochemistry from square-planar to octahedral around cobalt(II) and nickel(II) is observed. The bimetallic complexes are characterized by infrared, conductance, magnetic moments and electronic spectral data.
Page(s): 545-548
ISSN: 0975-0975(Online); 0376-4710(Print)
Appears in Collections:IJC-A Vol.30A(06) [June 1991]

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