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Title: Synthesis and characterization of ruthenium (II) complexes with mondtertiary phosphines and arsinies
Authors: Khan, M M Taqui
Reddy, M Satyanarayan
Issue Date: Mar-1991
Publisher: NISCAIR-CSIR, India
Abstract: The reaction of ruthenium (III) perchlorate with some monotertiary phosphines and arsines has been investigated. Ionic complexes of the type [RuL5 (CIO4)] (CIO4) where L = PPh3, As Ph3 PMe2Ph, AsMe2Ph or AsEt2Ph have been isolated. Some of these complexes react with nitric oxide to give complexes of the type [RuL5(NO)] (CIO4) where L = PPh3 or AsPh3. The complexes have been characterized on the basis of their elemental analysis, IR, NMR, conductiviity and magnetic moment data.
Page(s): 278-280
ISSN: 0975-0975(Online); 0376-4710(Print)
Appears in Collections:IJC-A Vol.30A(03) [March 1991]

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