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|Title:||Synthesis and characterization of ruthenium (II) complexes with mondtertiary phosphines and arsinies|
|Authors:||Khan, M M Taqui|
Reddy, M Satyanarayan
|Abstract:||The reaction of ruthenium (III) perchlorate with some monotertiary phosphines and arsines has been investigated. Ionic complexes of the type [RuL5 (CIO4)] (CIO4) where L = PPh3, As Ph3 PMe2Ph, AsMe2Ph or AsEt2Ph have been isolated. Some of these complexes react with nitric oxide to give complexes of the type [RuL5(NO)] (CIO4) where L = PPh3 or AsPh3. The complexes have been characterized on the basis of their elemental analysis, IR, NMR, conductiviity and magnetic moment data.|
|Appears in Collections:||IJC-A Vol.30A(03) [March 1991]|
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