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|Title:||Condensation of dimethyl malonate with benzal-4-acetylanilines: A chemoselective reaction|
|Keywords:||Benzal-4-acetylanilines;dimethyl malonate;dimethyl benzalmalonates;4-aminoacetophenone;benzaldehydes|
|Abstract:||Dimethyl malonate has reacted chemoselectively with carbon-nitrogen double bond of benzal-4-acetylanilines (1-8) leaving the carbon-oxygen double bond, considered to be more reactive, intact under reaction conditions, leading to the formation of mono addition-elimination products rather than bis attack at both the double bonds, even when the reaction has been carried out with two moles of dimethyl malonate.|
|Appears in Collections:||IJC-B Vol.48B(05) [May 2009]|
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