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Title: Condensation of dimethyl malonate with benzal-4-acetylanilines: A chemoselective reaction
Authors: Sidhu, Anjali
Rai, Mangat
Keywords: Benzal-4-acetylanilines;dimethyl malonate;dimethyl benzalmalonates;4-aminoacetophenone;benzaldehydes
Issue Date: May-2009
Publisher: CSIR
Abstract: Dimethyl malonate has reacted chemoselectively with carbon-nitrogen double bond of benzal-4-acetylanilines (1-8) leaving the carbon-oxygen double bond, considered to be more reactive, intact under reaction conditions, leading to the formation of mono addition-elimination products rather than bis attack at both the double bonds, even when the reaction has been carried out with two moles of dimethyl malonate.
Page(s): 735-736
ISSN: 0376-4699
Appears in Collections:IJC-B Vol.48B(05) [May 2009]

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