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Title: Chain initiation in persulphate initiated aqueous polymerization of methacrylonitrile under inert atmosphere and mechanism of persulphate decomposition
Authors: Guchhalt, Sukumar
Banerjee, Manoranjan
Konar, Ranajit Singha
Issue Date: Feb-1991
Publisher: NISCAIR-CSIR, India
Abstract: It has been found that the initial rate of persulphate decomposition in the persulphate concentration range of 0.40 x 10-2 to 3.00 x 10-2 moldm-3 and the monomer, methacrylonitrile (MAN), concentration range of 0.16 to 0.40 mol dm-3 may be given by the following expression,
-d(S2O/)/dt [MAN]1.38±0.05 X [S2](1.7±O.05 )
A reaction scheme has been suggested to explain the kinetic data.
Page(s): 130-135
ISSN: 0975-0975(Online); 0376-4710(Print)
Appears in Collections:IJC-A Vol.30A(02) [February 1991]

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