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|Title:||Synthesis and characterization of transition metal complexes of bishomodihydro-tetraaza(14)annulen|
|Authors:||Abushamleh, Ahmad S|
|Abstract:||Bishomodihydrotetraaza(14)annulene [H2(TAZM), IV], reacts with metal(ll) acetates under inert and nonaqueous conditions to afford the complexes [M(TAZM)], (VI, M=Ni, Co, Cu). Treatment of the Co(ll) complex with ammonia in the presence of air, results in the formation of an octahedral Co(Ill) complex which has been isolated as a tetraphenylborate salt [Co(TAZM)(NH3)2][BPh4). Elemental analyses, IR UV and mass spectrometry have been used to assign the structures of the complexes.|
|Appears in Collections:||IJC-A Vol.30A(01) [January 1991]|
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