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Title: Ruthenium(II) hydrido complexes of S-methyldithiocarbazates
Authors: Maurya, M R
Unny, I R
Alekar, N A
Gopinathan, S
Gopinathan, C
Issue Date: Dec-1997
Publisher: NISCAIR-CSIR, India
Abstract: Reactions of [RuHCI(CO)(PPh3)3] and [RuH2(CO)(PPh3) 3] with schiff bases (HL) derived from S-methyldithiocarbazate and pyridine-Z-aldchyde, 2-acetylpyridine, thiophene-2-aldehyde. 2- acetyl1hiophene and furan-z-aldehyde lead to the formation of neutral complexes of the type [RuX(CO)(PPh3)2L] (X = H or CI). The probable stereochemistries of the complexes have been established on the basis of elemental analysis. IR, 1H and 13C NMR studies. The triphenylphosphines are trans leaving CO and H or Cl cis to each other in the complexes.
Page(s): 1058-1062
ISSN: 0975-0975(Online); 0376-4710(Print)
Appears in Collections:IJC-A Vol.36A(12) [December 1997]

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