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Title: Synthesis and characterization of H-cardanol-triazole and fructose/galactose/mannose conjugates
Authors: Rao, H Surya Prakash
Kamalraj, M
Keywords: H-Cardanol;Monosaccharide;1,2,3-triazole;Amphiphile;CuAAC
Issue Date: May-2017
Publisher: NISCAIR-CSIR, India
Abstract: Conjugates of hydrogenated cardanol (H-cardanol; a fine chemical derived from cashew nut shell liquid) and common hexoses like fructose and galactose have been synthesized by applying azide alkyne 1,3-dipolar cycloaddition (CuAAC) reaction for 1,4-disubstituted triazole linker generation. The resulting conjugates namely, fructose-1,2,3-triazole-H-cardanol (FTHCC) and galactose-1,2,3-triazole-H-cardanol (GaTHCC) have hydrophilic monosaccharide head and hydrophobic 15C hydrocarbon tail which make them amphiphilic. Attempted synthesis of mannose-triazole-H-cardanol conjugate (MTHCC) results in glycoside hydrolysed product. Both FTHCC and GaTHCC display aggregation behaviour in chloroform and water-methanol but do not form a gel.
Page(s): 551-559
ISSN: 0975-0983(Online); 0376-4699(Print)
Appears in Collections:IJC-B Vol.56B(05) [May 2017]

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