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Title: Homolytic displacement at carbon in organocobaloximes: Part 9­-Reactions of organocobaloximes with thiophene 2-sul-phonylchloride
Authors: Gupta, B D
Das, Indira
Issue Date: Dec-1996
Publisher: NISCAIR-CSIR, India
Abstract: Several allyl (both cyclic and acyclic), allenyl, hexenyl and propargylcobaloximes react regiospecifically with thiophone-2-sulphonyl chloride under thermal and photochemical conditions to give the corresponding sulphones. The reaction is believed to take place by the attack of the sulphur radical on the terminal carbon of the organocobaloxime with the displacement of cobaloxime(II).
Page(s): 1111-1113
ISSN: 0975-0975(Online); 0376-4710(Print)
Appears in Collections:IJC-A Vol.35A(12) [December 1996]

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