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Title: Synthesis, characterization and reactions of cluster complexes Fe4(HSCH2CH2SH)2(CO)12 Fe2(HSCH2CH2SH)(CO)8 and Fe2(HSCH2CH2SH)(CO)6
Authors: Ullah, S S
Alam, F R
Ishizuka, Y
Goto, M
Issue Date: Nov-1996
Publisher: NISCAIR-CSIR, India
Abstract: An iron-sulphur cluster complex, Fe4(HSCH2CH2SH)2(CO)12 (I) has been synthesized by thermal reaction of 1,2-ethanedithiol, HSCH2CH2SH with Na2[Fe(CO)4] and Fe3(CO)12 separately. Complex I is reacted with NaOEt in CH2Cl2 and monitored by IR to observe the formation of cluster anion [(Fe4S4(CH2-CH2)2)]·-n (n= 1 to 4). The treatment of 1,2-ethanedithiol with Cp2TiCl2 and Na2[Fe(CO)4] at room temperature and refluxing condition gives Fe2(HSCH2CH2SH)(CO)8 (II) and Fe2(HSCH2CH2SH)(CO)6(III) respectively. The complexes have been characterized by elemental analysis, IR, PMR and mass spectral data.
Page(s): 930-934
ISSN: 0975-0975(Online); 0376-4710(Print)
Appears in Collections:IJC-A Vol.35A(11) [November 1996]

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