Please use this identifier to cite or link to this item: http://nopr.niscair.res.in/handle/123456789/41495
Title: Kinetics of oxidation of tris-(2,2' -bipyridyI)cobalt(II) by iron(III)- 2,2' -bipyridyl complex-Micellar effect of sodium dodecylsulphate
Authors: Rao, P V Subba
Rao, G Krishna
Ramakrishna, K
Rambabu, G
Satyanarayana, A
Issue Date: Nov-1996
Publisher: NISCAIR-CSIR, India
Abstract: lron(III)-2,2' -bipyridyl complex obtained, in situ, by direct mixing of iron(III) and 2,2' -bipyridyl, oxidises I Co(Bipy) and the reaction is markedly accelerated by sodium dodecylsulphate. The rate- [surfactant] profile exhibits a maximum. The kinetic analysis of the micellar effect has been carried out using Berezin's approach. The binding constants of 2,2¢-bipyridyl and Co(Bipy) have been determined.
Page(s): 969-973
URI: http://nopr.niscair.res.in/handle/123456789/41495
ISSN: 0975-0975(Online); 0376-4710(Print)
Appears in Collections:IJC-A Vol.35A(11) [November 1996]

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