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|Title:||Kinetics of oxidation of tris-(2,2' -bipyridyI)cobalt(II) by iron(III)- 2,2' -bipyridyl complex-Micellar effect of sodium dodecylsulphate|
|Authors:||Rao, P V Subba|
Rao, G Krishna
|Abstract:||lron(III)-2,2' -bipyridyl complex obtained, in situ, by direct mixing of iron(III) and 2,2' -bipyridyl, oxidises I Co(Bipy) and the reaction is markedly accelerated by sodium dodecylsulphate. The rate- [surfactant] profile exhibits a maximum. The kinetic analysis of the micellar effect has been carried out using Berezin's approach. The binding constants of 2,2¢-bipyridyl and Co(Bipy) have been determined.|
|Appears in Collections:||IJC-A Vol.35A(11) [November 1996]|
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