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Title: Synthesis and characterization of seven-coordinated polymeric mono[anti-cis-bis(2-hydroxy-1-naphthaldehyde) oxaloyldihydrazonato]monoaquobis-cis-dioxomolybdenum(VI)dihydrate complex
Authors: Lal, R A
Adhikari, S
Issue Date: Jul-1996
Publisher: NISCAIR-CSIR, India
Abstract: The title compound synthesized from the reaction of MoO2(acac)2 with bis(2-hydroxy-1-naphthaldehyde)- oxaloyldihydrazone in ethanol-acetonitrile in 3:1 molar ratio under reflux is proposed to be a hexamer in which Iigands are arranged in sets of three in two parallel planes one above the other. The intraplanar metal atoms are bonded to each other by naphthoxo-bridges whereas the interplanar metal atoms are bonded to each other by Mo =O- - -Mo type of bridging. The anti-cis-configuration of the dihydrazone moieties leads to the chair conformation of the complex.
Page(s): 607-610
ISSN: 0975-0975(Online); 0376-4710(Print)
Appears in Collections:IJC-A Vol.35A(07) [July 1996]

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