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Title: Synthesis and characterization of mixed ligand complexes of cobalt(II) and nickel( II) containing trans-[14]-dieneand organic monobasic acids
Authors: Islam, M Saidul
Pal, S C
Ahmed, Sayenuddin
Mofizuddin, M
Issue Date: Jul-1996
Publisher: NISCAIR-CSIR, India
Abstract: A number of mixed ligand complexes of cobalt(II) and nickel(Il) containing trans-[14]-dieneand some organic monobasic acids of composition, [M((L')2L"][M = cobalt(II) and nickel(II), L' = acetic acid, propionic acid, butyric acid and benzoic acid and L" = trans- [14]-diene] have been isolated and characterized by elemental analyses, conductivity and magnetic measurements, IR and electronic spectral studies. The molar conductance values reveal that the complexes are 2:1 electrolytes in DMF. The magnetic data, IR and electronic spectra of the complexes are consistent with the high spin six-coordinated octahedral geometry for cobalt(II) complexes and tetragonal geometry for nickel(II) complexes of D4h symmetry.
Page(s): 617-619
ISSN: 0975-0975(Online); 0376-4710(Print)
Appears in Collections:IJC-A Vol.35A(07) [July 1996]

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