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Title: σ-Bonded organometallic complexes of iron and cobalt derived from 2-bromomethylnaphthalene
Authors: Alam, F R
Azam, K A
Kabir, S E
Ullah, S S
Issue Date: Apr-1996
Publisher: NISCAIR-CSIR, India
Abstract: The monoanionic metal carbonylate Na[Fe(η5-C5H5) (CO)2] reacts with 2-bromomethylnaphthalene at ambient temperature to give [(σ-C10H7CH2)Fe(η5-C5H5)(CO)2] (I) whereas with Na[Co(CO)4] at room temperature [(σ-C10H7CH2)Co(CO)4](II) is obtained. Irradiation of (I) yields [(η5-C5H5)Fe(CO)2]2 (III) and C10H7CH2CH2C10H7 (IV). The compounds have been characterized by IR. PMR, mass spectroscopic data and elemental analysis.
Page(s): 317-319
ISSN: 0975-0975(Online); 0376-4710(Print)
Appears in Collections:IJC-A Vol.35A(04) [April 1996]

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