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Title: A low-spin carboxyl-bonded iron(III) complex
Authors: Karmakar, Soma
Chakravorty, Animesh
Issue Date: Feb-1996
Publisher: NISCAIR-CSIR, India
Abstract: The ligand HON =C(Ph)N =N - C6H4CO2H (H2L) has afforded the low-spin (S = 1/2) iron(lll) complex, Et4N[Fe(PhL)2] which has been structurally characterised revealing the presence of cis-FeN4O2 coordination sphere. Carboxyl-bonded low-spin iron(lll) species are very rare. Spin-pairing contracts metal radius, the Fe - N and Fe - O lengths being significantly shorter than those in representative high-spin complexes.
Page(s): 85-86
ISSN: 0975-0975(Online); 0376-4710(Print)
Appears in Collections:IJC-A Vol.35A(02) [February 1996]

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