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Title: Syntheses and spectroscopic studies of mono- and dicyclopentadienyl titanium (IV)/zirconium (IV) derivatives with S-alkyl-β-N-(acetylferrocenyl) methylene dithiocarbazates
Authors: Srivastava, B K
Srivastava, S K
Pandey, O P
Sengupta, S K
Issue Date: Jan-1996
Publisher: NISCAIR-CSIR, India
Abstract: The reactions of dicyclopentadienyl titanium (IV)/ zirconium (IV) dichloride and monocyclopentadienyl titanium (IV) trichloride with thio-Schiff bases (LH), derived by the condensation of S-methyl/ethyl/propyl dithiocarbazic acid and acetylferrocene, have been carried out under inert atmosphere and anhydrous conditions in different stoichiometric ratios. Complexes of the types Cp2M(L)Cl, CpM(L)2Cl (M = Ti(IV) or Zr-(IV)), CpTi(L)CI2, CpTi(L)2Cl are synthesized and characterized by elemental analysis, electrical conductance, magnetic moment and spectral (electronic, infrared, 1H NMR) data.
Page(s): 57-59
ISSN: 0975-0975(Online); 0376-4710(Print)
Appears in Collections:IJC-A Vol.35A(01) [January 1996]

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