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Title: Kinetics and mechanism of oxidation of aliphatic acetals with N-chlorobenzamide
Authors: Ahamed, K A Basheer
Issue Date: Mar-1997
Publisher: NISCAIR-CSIR, India
Abstract: The oxidation kinetics of thirteen aliphatic acetals of normal aliphatic aldehydes and substituted aliphatic aldehydes with aliphatic and substituted aliphatic. as well as with aromatic alcohols by N-chlorobenzamide (NCB) in aqueous acetic acid medium follows first order and zero order dependence in [NCB] and [acetal] respectively and yields the corresponding esters as the main product of oxidation. (H2OCl)+ has been postulated as the oxidizing species.
Page(s): 222-224
ISSN: 0975-0975(Online); 0376-4710(Print)
Appears in Collections:IJC-A Vol.36A(03) [March 1997]

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