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|Title:||Kinetics and mechanism of oxidation of aliphatic acetals with N-chlorobenzamide|
|Authors:||Ahamed, K A Basheer|
|Abstract:||The oxidation kinetics of thirteen aliphatic acetals of normal aliphatic aldehydes and substituted aliphatic aldehydes with aliphatic and substituted aliphatic. as well as with aromatic alcohols by N-chlorobenzamide (NCB) in aqueous acetic acid medium follows first order and zero order dependence in [NCB] and [acetal] respectively and yields the corresponding esters as the main product of oxidation. (H2OCl)+ has been postulated as the oxidizing species.|
|Appears in Collections:||IJC-A Vol.36A(03) [March 1997]|
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