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|Title:||Ion association and solvation of octahedral Co(III) complexes in water +DMSO mixtures at different temperatures|
|Authors:||Dash, U N|
Pasupalak, N N
|Abstract:||Viscosities and conductometric studies have been made for the solutions of carbonatopentaamine Co(III) nitrate, aquopentaamine Co(III) nitrate, oxalatopentaamine Co(III) nitrate, malonatopentaamine Co(III) nitrate and succinatopentaamine Co(III) nitrate in water + DMSO mixtures at different temperatures. The limiting molar conductance (Ʌo) and association constant (KA) for these complexes in water + DMSO mixtures are evaluated using Shedlovsky and Fuoss- Kraus techniques. The results are discussed in terms of ion-ion and ion-solvent interactions in these solvents.|
|Appears in Collections:||IJC-A Vol.36A(01) [January 1997]|
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