Please use this identifier to cite or link to this item: http://nopr.niscair.res.in/handle/123456789/40445
Title: Hydrogenation kinetics and mechanism of stilbene, cinnamaldehyde and cinnamic acid by anchored montmorillonitebipyridinepalladium(ll) acetate
Authors: Swamy, Katthi Venkata
Sadanand, D Thomas
Ramesh, B
Saiprakash, P K
Issue Date: Jan-1997
Publisher: NISCAIR-CSIR, India
Abstract: Hydrogenation of olefinic compounds catalysed by anchored catalysts is of current interest. A detailed kinetic study of the hydrogenation of some olefinic compounds over anchored montmorillonitebipyridinepalladium(II) acetate catalyst which belongs to a new generation catalytic system is presented. The effects of substrate concentration, partial pressure of hydrogen, catalyst concentration, solvent and temperature have been studied. Based on the results a mechanism is proposed, rate law derived and the corresponding thermodynamic parameters have been evaluated. Product analysis is confirmed by H-NMR, IR and GLC.
Page(s): 98-101
URI: http://nopr.niscair.res.in/handle/123456789/40445
ISSN: 0975-0975(Online); 0376-4710(Print)
Appears in Collections:IJC-A Vol.36A(01) [January 1997]

Files in This Item:
File Description SizeFormat 
IJCA 36A(1) 98-101.pdf382.38 kBAdobe PDFView/Open


Items in NOPR are protected by copyright, with all rights reserved, unless otherwise indicated.