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Title: Hydrogenation kinetics and mechanism of stilbene, cinnamaldehyde and cinnamic acid by anchored montmorillonitebipyridinepalladium(ll) acetate
Authors: Swamy, Katthi Venkata
Sadanand, D Thomas
Ramesh, B
Saiprakash, P K
Issue Date: Jan-1997
Publisher: NISCAIR-CSIR, India
Abstract: Hydrogenation of olefinic compounds catalysed by anchored catalysts is of current interest. A detailed kinetic study of the hydrogenation of some olefinic compounds over anchored montmorillonitebipyridinepalladium(II) acetate catalyst which belongs to a new generation catalytic system is presented. The effects of substrate concentration, partial pressure of hydrogen, catalyst concentration, solvent and temperature have been studied. Based on the results a mechanism is proposed, rate law derived and the corresponding thermodynamic parameters have been evaluated. Product analysis is confirmed by H-NMR, IR and GLC.
Page(s): 98-101
ISSN: 0975-0975(Online); 0376-4710(Print)
Appears in Collections:IJC-A Vol.36A(01) [January 1997]

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