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Title: Synthesis and characterization of some heterobimetallic complexes of 1,1-dithiolates
Authors: Aggarwal, R C
Mitra, Rashmi
Issue Date: Jan-1994
Publisher: NISCAIR-CSIR, India
Abstract: A few heterobimetallic; complexes of the type M[M'(L-L2 [where L-L= 1, 1-cyanocarboethoxy-2,2ethylene dithiolate (CED); M = Co(ll), Ni(II), Cu(II) M' = Zn(II), Cd(II), Hg(II); for L-L = 1, 1-dicarboethoxy- 2,2-ethylene dithiolate (DED); M = Co(II), Ni(II), eu(II), M' = Zn(II), Hg(II)] have been prepared and characterized by elemental analysis, magnetic susceptibility, electronic and infrared spectroscopic measurements. The magnetic and electronic spectral studies indicate a square planar geometry around Co(ll), Ni(ll) and Cu(ll) while infrared spectra show bidentate behaviour of the ligands.
Page(s): 55-57
ISSN: 0975-0975(Online); 0376-4710(Print)
Appears in Collections:IJC-A Vol.33A(01) [January 1994]

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