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|Title:||Synthesis of monoligate ditertiary phosphino complexes of niobium(IV) chloride and their bonding interaction with Mo( CO)6|
Vermani, O P
Narula, A K
|Abstract:||The reduction of niobium chloride with aluminium or zinc in the presence of various ditertiary phosphines give biligate complexes of the type , while sodium amalgam reduction of NbCI5 give monoligate complexes of the type . The complex [Nb2CI8(dppe)4] on further treatment with Mo(CO)6 yielded heteronuclear bimetallic complex . The complexes have been characterized by elemental analysis, IR and NMR spectral studies.|
|Appears in Collections:||IJC-A Vol.34A(11) [November 1995]|
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