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Title: Synthesis of monoligate ditertiary phosphino complexes of niobium(IV) chloride and their bonding interaction with Mo( CO)6
Authors: Sharma, Sangeeta
Gupta, Shamma
Vermani, O P
Narula, A K
Issue Date: Nov-1995
Publisher: NISCAIR-CSIR, India
Abstract: The reduction of niobium chloride with aluminium or zinc in the presence of various ditertiary phosphines give biligate complexes of the type , while sodium amalgam reduction of NbCI5 give monoligate complexes of the type . The complex [Nb2CI8(dppe)4] on further treatment with Mo(CO)6 yielded heteronuclear bimetallic complex . The complexes have been characterized by elemental analysis, IR and NMR spectral studies.
Page(s): 883-887
ISSN: 0975-0975(Online); 0376-4710(Print)
Appears in Collections:IJC-A Vol.34A(11) [November 1995]

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