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|Title:||Ru(lll) catalysed oxidation of a-hydroxy acids by iodate- A kinetic study|
|Abstract:||Ru(III) acts as a catalyst in the oxidation of a-hydroxy acids by iodate. The reaction is found to be first order in [oxidant], and [Ru(III)] and fractional order in [hydroxy acid]. H+ ions retard the reaction. A mechanism, involving the formation of a complex between Ru(III) and hydroxy acid which interacts with HIO3 in a slow step, is proposed.|
|Appears in Collections:||IJC-A Vol.34A(11) [November 1995]|
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