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Title: Ru(lll) catalysed oxidation of a-hydroxy acids by iodate- A kinetic study
Authors: Brahmaiah, A
Manikyamba, P
Issue Date: Nov-1995
Publisher: NISCAIR-CSIR, India
Abstract: Ru(III) acts as a catalyst in the oxidation of a-hydroxy acids by iodate. The reaction is found to be first order in [oxidant], and [Ru(III)] and fractional order in [hydroxy acid]. H+ ions retard the reaction. A mechanism, involving the formation of a complex between Ru(III) and hydroxy acid which interacts with HIO3 in a slow step, is proposed.
Page(s): 900-903
ISSN: 0975-0975(Online); 0376-4710(Print)
Appears in Collections:IJC-A Vol.34A(11) [November 1995]

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