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Title: Spectroscopic studies of dioxomolybdenum (VI) complexes of polyfunctional dihydrazones containing amide, azomethine, phenol and active methylene functions.
Authors: Lal, R A
Kumar, A
Issue Date: Oct-1998
Publisher: NISCAIR-CSIR, India
Abstract: Bis (acetylacetonato) dioxomolybdenum (VI) reacts with disalicylaldehyde malonoyldihydrazone (CH2 salmlhH4.) to yield an unstable monomeric yellow complex of the type [(MoO2)2 (CHsalmlhH4.) (H2O)2].H2O {complex (A)} which is transformed into an intermediate complex [(MoO2)2 (CHsalmlhH)(H2O)]2. 4H2O {complex (AB)} after sometime. The reaction mixture ultimately yields a stable brown isomer complex [(MoO2)2 (CH2salmlh (H2O)]2 4H2O {complex (B)}. All the products have been characterized by various physico-chemical techniques and infrared and 1H NMR spectroscopic studies.
Page(s): 921-926
ISSN: 0975-0975(Online); 0376-4710(Print)
Appears in Collections:IJC-A Vol.37A(10) [October 1998]

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