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Title: Silyl-nitrogen compounds: Part VI-Reactions of lithium tris (trimethylsilyl)hydrazine with non- metallic halides
Authors: Vasisht, S K
Kaushal, Jyotsna
Issue Date: Jul-1998
Publisher: NISCAIR-CSIR, India
Abstract: Lithium tris (trimethylsilyl) hydrazine (Me3Si)2N-N(SiMe3)Li (1) reacts with non-metallic halides EXn to form bis tris (trimethylsilyl)hydrazino in derivatives [(Me3Si)3N2]2EXn-2 where E=B, X=F. n=3; E=C, X=Br, n=4; E=Si, X=CI, n=4 and E=P, X=CI, n=5. Non-metallic monohydrazino derivatives (Me3Si)3 N2EXn-l are formed in cases of BF3, Me2SiCb, PCb, PBr3, AsCl3 and Et2NAsCl2.
Page(s): 626-630
ISSN: 0975-0975(Online); 0376-4710(Print)
Appears in Collections:IJC-A Vol.37A(07) [July 1998]

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