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|Title:||Ion association and solvation of silver monocarboxylates in water + mannitol and water + sorbitol mixtures at different temperatures: A conductivity study|
|Authors:||Dash, U N|
Pattanaik, E R
|Abstract:||The conductivities of silver acetate, silver propionate and silver benzoate have been measured in water + 5 wt% mannitol and water + 5 wt% sorbitol at 20, 25, 30 and 35°C, and analysed using Fuoss-Hsia equation in the form of Fernandez-Prini coefficients and Shedlovsky and Fuoss-Kraus extrapolation techniques for calculating the association parameters (Λ 0 and KA). A comparison of these parameters revealed that the Shedlovsky method is superior to other methods and predicted better association constants for the silver monocarboxylates in these aqueous isomeric solvents.|
|Appears in Collections:||IJC-A Vol.34A(07) [July 1995]|
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