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Title: Ion association and solvation of silver monocarboxylates in water + mannitol and water + sorbitol mixtures at different temperatures: A conductivity study
Authors: Dash, U N
Pattanaik, E R
Issue Date: Jul-1995
Publisher: NISCAIR-CSIR, India
Abstract: The conductivities of silver acetate, silver propionate and silver benzoate have been measured in water + 5 wt% mannitol and water + 5 wt% sorbitol at 20, 25, 30 and 35°C, and analysed using Fuoss-Hsia equation in the form of Fernandez-Prini coefficients and Shedlovsky and Fuoss-Kraus extrapolation techniques for calculating the association parameters (Λ 0 and KA). A comparison of these parameters revealed that the Shedlovsky method is superior to other methods and predicted better association constants for the silver monocarboxylates in these aqueous isomeric solvents.
Page(s): 556-562
ISSN: 0975-0975(Online); 0376-4710(Print)
Appears in Collections:IJC-A Vol.34A(07) [July 1995]

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