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Title: X-ray structural and spectroscopic studies of a mononuclear copper(II) complex with axial and equatorial phenolate ligation
Authors: Bandyopadhyay, Prasun
Ghosh, Pradyut
Bharadwaj, Parimal K.
Issue Date: Jul-1998
Publisher: NISCAIR-CSIR, India
Abstract: A tridentate Schiff base obtained by condensing salicylaldehyde with 2-dimethylamino-ethylamine in 1:1 molar ratio readily forms a bis-complex with cupric perchlorate hexahydrate in methanol in the presence of KOH. The complex crystallizes from methanol in the monoclinic space group P21/c with a = 11.221 (3), b = 19.462(2), c = 13.062(3), β= 109.36(4)°, Z= 4, R = 0.050, R' = 0.045 and goodness-of-fit = 2.551.
Page(s): 639-643
ISSN: 0975-0975(Online); 0376-4710(Print)
Appears in Collections:IJC-A Vol.37A(07) [July 1998]

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