Please use this identifier to cite or link to this item: http://nopr.niscair.res.in/handle/123456789/40072
Title: Synthesis and characterization of nonaisopropoxodizirconatotin(IV) complexes
Authors: Mathur, Sanjay
Singh, Anirudh
Mehrotra, Ram C
Issue Date: Jun-1995
Publisher: NISCAIR-CSIR, India
Abstract: A number of novel heteroleptic nonaisopropoxodizirconatotin(IV) complexes of the type [Sn{Zr2(OPri)9}nCl4-n](where n= 1-3) have been synthesised by the reactions of SnCl4 with KZr2(OPri)9,in benzene in requisite (1:1, 1:2, or 1:3) molar ratios. Replacement of chloride in these derivatives by an appropriate alkoxide affords volatile, heterobimetallic derivatives of the type [Sn{Zr2(OPri )9}n(OR)4-n] (R =Pri, But, n = 2 or 3). These novel heterometal alkoxides have been characterized by elemental analyses, molecular weight measurements, IR and multinuclear (1H, 13C and 119Sn) NMR spectral studies.
Page(s): 454-458
URI: http://nopr.niscair.res.in/handle/123456789/40072
ISSN: 0975-0975(Online); 0376-4710(Print)
Appears in Collections:IJC-A Vol.34A(06) [June 1995]

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