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Title: Synthesis and characterization of complexes [5-CpFe(CO)2]2SiMe2 and [(5-Cp)4Fe4(CO)2(SiMe2)2]
Authors: Safiullah, Syed
Kundu, Kalipada
Karim, M Manzurul
Bhakta, Babul
Issue Date: May-1995
Publisher: NISCAIR-CSIR, India
Abstract: Na[5-CpFe(CO)2] reacts with SiMe2Cl2 (2:1 molar ratio) in THF at ~ 0°C to give the iron-silicon cluster complex [(5-Cp)4Fe4(CO)2(SiMe2)2] (II) in addition to the simple complex {5-CpFe(CO)2]2SiMe2 (I). The complex (II) has a tetrahedral framework of four iron atoms with bridging CO and SiMe2 units and the structure is highly symmetrical.
Page(s): 398-399
ISSN: 0975-0975(Online); 0376-4710(Print)
Appears in Collections:IJC-A Vol.34A(05) [May 1995]

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