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Title: Synthesis and characterization of some novel mixed-ligand cyanonitrosyl {CoNO}8 complexes of Co(I) with potential mono-, bi- and tri-dentate nitrogen donors
Authors: Maurya, R C
Mishra, D D
Mukherjee, S
Dubey, J
Issue Date: May-1995
Publisher: NISCAIR-CSIR, India
Abstract: Some novel hexa-coordinated mixed-ligand cyanonitrosyl complexes of cobalt(I) having the general formula K2[Co(NO)(CN)4- (L)] (where L= nitrogen donor organic compound have been prepared by the interaction of K2[Co(NO)(CN)4(H2O)]·H2O with L in aqueous- ethanolic medium. The products have been characterized by elemental analyses, molar conductances, magnetic measurements, infrared spectral studies, 1H NMR, UV-vis and thermogravimetric analysis. A tetragonally distorted octahedral structure has been proposed.
Page(s): 403-406
ISSN: 0975-0975(Online); 0376-4710(Print)
Appears in Collections:IJC-A Vol.34A(05) [May 1995]

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