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|Title:||Hydrolysis of schiff bases in (CTAB-CHCl3-H2O) reversed micelles: Role of spacers|
Dash, P K
Mishra, B K
Behera, G B
|Abstract:||The schiff bases .of the type (p-C 16H33O-C6H4CH=N)2(CH2)m (1, m=O, 2, 3, 4 and 6) and the ortho isomer (2, m = 0, 2, 4, 6) have been synthesized and the hydrolysis of these compounds have been studied in CTAB-CHCl3,-H2O reversed micellar system under acidic condition. Significant variation of the reaction rate has been observed due to variation in the number of methylene groups in the spacer and due to the change in the position of the cetyloxy group. Difference in the rate of disappearance of schiff base and appearance of the product is ascribed to a mechanism involving a carbinolamine intermediate.|
|Appears in Collections:||IJC-A Vol.34A(03) [March 1995]|
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