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Title: Synthesis and characterization of trans-[OsBr4(SMe2)2]: The first monothioether complex of osmium (IV)
Authors: Pramanik, Kausikisankar
Ghosh, Prasanta
Chakravorty, Animesh
Issue Date: Feb-1998
Publisher: NISCAIR-CSIR, India
Abstract: The title complex has been synthesized in excellent yield by oxidizing mer-[OSBr3(SMe2)3] with excess bromine in benzene at room temperature. Its geometry is characterized by X-ray crystallography. The OsIV/Oslll reduction potential is 0.45 V vs. SCE.
Page(s): 95-96
ISSN: 0975-0975(Online); 0376-4710(Print)
Appears in Collections:IJC-A Vol.37A(02) [February 1998]

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