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Title: Synthesis and characterization of some novel mixed-ligand cyanonitrosyl {MnNO}6 complexes of manganese (I) with biologically active oxygen donor 2- or 3-pyrazoline-5-one derivatives
Authors: Maurya, R C
Verma, R
Issue Date: Feb-1998
Publisher: NISCAIR-CSIR, India
Abstract: A series of novel mixed-ligand cyanonitrosyl complexes on Mn(I) have been synthesized by the reaction of pentacyanonitrosylmanganate (I) anion ([Mn(NO)(CN)5]3-) with 2- or 3- pyrazoline -5- one derivatives. The products which have been characterized by elemental analysis, molar conductance measurements, magnetic susceptibility measurements, thermogravimetric analysis, electronic and IR spectral studies, have the general formula [Mn(NO) (CN) (L)2 (H2O)] (where L = 2- or 3- pyrazoline -5-one derivatives). Octahedral configuration with low-spin {Mn(NO)}6 species has been suggested for these complexes.
Page(s): 147-150
ISSN: 0975-0975(Online); 0376-4710(Print)
Appears in Collections:IJC-A Vol.37A(02) [February 1998]

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