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IJC-A Vol.48A(04) [April 2009] >


Title: Synthesis and chelation ion exchange properties of 2, 4-dihydroxyacetophenone-biuret-formaldehyde terpolymer resin
Authors: Rahangdale, S S
Gurnule, W B
Zade, A B
Keywords: Ion exchange
Terpolymers
Polymer resins
Resins
Distribution ratio
Issue Date: Apr-2009
Publisher: CSIR
IPC CodeInt. Cl.8 B01J 39/00
Abstract: The terpolymer resin 2, 4-dihydroxyacetophenone-biuret-formaldehyde has been synthesized by the condensation of 2, 4-dihydroxyacetophenone and biuret with formaldehyde in 2:1:3 molar ratios in presence of 2M hydrochloric acid as catalyst. UV-visible, IR and proton NMR spectral studies have been carried out to elucidate the structure of the resin. The terpolymer has proved to be a selective chelating ion exchange polymer for some metals. Chelating ion exchange properties of this polymer have been studied for Fe3+, Cu2+, Ni2+, Co2+, Zn2+, Cd2+ and Pb2+ ions. Batch equilibrium method has been employed to study the selectivity of metal ion uptake and distribution coefficient over a wide pH range and in media of varying ionic strengths. The polymer shows higher selectivity for Fe3+ and Cu2+ ions than for Ni2+, Co2+, Zn2+, Cd2+ and Pb2+ ions. Study of distribution ratio as a function of pH indicates that the amount of metal ion uptake by resin increases with the increasing pH of the medium.
Page(s): 531-535
ISSN: 0376-4710
Source:IJC-A Vol.48A(04) [April 2009]

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