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http://nopr.niscair.res.in/handle/123456789/35171| Title: | Bifunctional organocatalysts for the synthesis of jasminaldehyde and their derivatives |
| Authors: | Ganga, Venkata Subba Rao Abdi, Sayed H R Kureshy, Rukhsana I Khan, Noor-ul H Bajaj, Hari C |
| Keywords: | Catalysis;Organocatalysts;Bifunctional organocatalysts;Cross-aldol condensation;Jasminaldehyde;Heptanal |
| Issue Date: | Aug-2016 |
| Publisher: | NISCAIR-CSIR, India |
| Abstract: | L-Proline in the presence of benzoic acid is found to be an effective catalytic system for the cross-aldol condensation of benzaldehyde with 1-heptanal under solvent free condition amongst the several amino acids screened for this reaction. Under the optimized reaction conditions, the desired product (e.g. jasminaldehyde) is formed up to 96% selectivity in one hour using the desired arylaldehyde: 1-alkanaldehyde ratio as low as 2:1 under controlled addition of 1-alkanaldehyde. |
| Page(s): | 950-955 |
| URI: | http://nopr.niscair.res.in/handle/123456789/35171 |
| ISSN: | 0975-0975(Online); 0376-4710(Print) |
| Appears in Collections: | IJC-A Vol.55A(08) [August 2016] |
Files in This Item:
| File | Description | Size | Format | |
|---|---|---|---|---|
| IJCA 55A(8) 950-955.pdf | 118.41 kB | Adobe PDF | View/Open |
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